five

Bioinspired Synthesis of Hirsutellones A, B, and C

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Bioinspired_Synthesis_of_Hirsutellones_A_B_and_C/2597683
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The total synthesis of hirsutellones A (1), B (2), and C (3) has been achieved through a bioinspired late-stage sequence starting from advanced intermediate 6. The sequence proceeded via labile intermediate 17,1′-dehydrohirsutellone B (5) and delivered, in addition to the natural products (1–3), hirsutellone analogue 1′,2′,17-epi-hirsutellone C (1′,2′,17-epi-3).
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2016-02-22
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