Facile Synthesis of Nitrogen-Containing Six-Membered Benzofuzed Phenophosphazinine Oxides and Studies of the Photophysical Properties
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https://figshare.com/articles/dataset/Facile_Synthesis_of_Nitrogen-Containing_Six-Membered_Benzofuzed_Phenophosphazinine_Oxides_and_Studies_of_the_Photophysical_Properties/11710887
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资源简介:
A facile synthesis of nitrogen-containing
six-membered benzofuzed
phosphacycles has been described. This cyclization reaction triggered
by Tf2O provides an expedient protocol of phosphacycles
with a simple operation at mild conditions. The preliminary photophysical
studies of these novel materials reveal that the fluorescence intensity
enhances with the molecular aggregation in the solid state and that
the introduction of the sterically bulky phenanthrene group into the
phosphacycles allows a significant increase in the fluorescence quantum
yield.
创建时间:
2020-01-17



