Stoichiometric Metal-Free Reduction of CO in Syn-Gas
收藏Figshare2016-02-19 更新2026-04-29 收录
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资源简介：
Reaction of a 2:1 mixture of B(C6F5)3 and tBu3P with syn-gas results in the stoichiometric reduction of CO to give a formyl derivative which reacts further via an epoxy-borate intermediate to capture CO, affording a heterocylic alkoxyborate. Heating the reaction prompts reaction with H2 to give a borane-oxy-borate derivative, the product of C–O bond cleavage.
创建时间：
2016-02-19
