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Allenyl Azide Cycloaddition Chemistry: Application to the Total Synthesis of (±)-Meloscine

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Allenyl_Azide_Cycloaddition_Chemistry_Application_to_the_Total_Synthesis_of_Meloscine/2553910
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资源简介:
The pentacyclic alkaloid (±)-meloscine was prepared in 19 steps through a reaction sequence that features a putative azatrimethylenemethane intermediate, generated through cascade cyclization of an allenyl azide substrate, to deliver the core azabicyclo[3.3.0]octadiene substructure. Subsequent manipulation of the peripheral functionality then delivered (±)-meloscine.
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2016-02-22
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