Synthesis of α,α-Disulfenylated Aldehydes via Oxidative Transformation of Tertiary Amines
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https://figshare.com/articles/dataset/Synthesis_of_Disulfenylated_Aldehydes_via_Oxidative_Transformation_of_Tertiary_Amines/2112577
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资源简介:
A method for the copper-catalyzed
regioselective β-functionalization
of tertiary amines with thiophenols has been developed. The control
experiments and primary studies show that a thiyl radical is involved
in the reaction, and the method provides a novel and direct approach
to synthesize C(sp3)–S bonds without a directing
group under ligand-free conditions.
创建时间:
2016-02-12



