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Phenyliodine(III) Bis(trifluoroacetate) (PIFA)-Promoted Synthesis of Bodipy Dimers Displaying Unusual Redox Properties

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Phenyliodine_III_Bis_trifluoroacetate_PIFA_Promoted_Synthesis_of_Bodipy_Dimers_Displaying_Unusual_Redox_Properties/2663140
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Phenyliodine(III) bis(trifluoroacetate) (PIFA) in conjunction with a Lewis acid promotes C−C coupling of Bodipy monomers leading to mixtures of various oligomers. When a single position is blocked with an iodo or phenyl group, formation of the dimer is favored. These dimers display two successive oxidation and two reduction waves separated on average by 260 and 130 mV, respectively, corresponding to each Bodipy subunit.
创建时间:
2016-02-23
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