Reactivity of [Cp<sub>2</sub>Ti(CO)<sub>2</sub>] and B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>: Formation of the Acylborane Complexes [Cp<sub>2</sub>Ti(CO)(η<sup>2</sup>-OCB(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>)] and [Cp<sub>2</sub>Ti(THF)(η<sup>2</sup>-OCB(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>)]
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数据链接：
https://figshare.com/articles/dataset/Reactivity_of_Cp_sub_2_sub_Ti_CO_sub_2_sub_and_B_C_sub_6_sub_F_sub_5_sub_sub_3_sub_Formation_of_the_Acylborane_Complexes_Cp_sub_2_sub_Ti_CO_sup_2_sup_-OCB_C_sub_6_sub_F_sub_5_sub_sub_3_sub_and_Cp_sub_2_sub_Ti_THF_sup_2_sup_-OCB_C_sub_6_sub_F_sub_5_sub_sub/3775695数据链接链接失效反馈
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资源简介：
The reaction of [Cp2Ti(CO)2] with B(C6F5)3 leads, surprisingly, as revealed by X-ray structure determination to the unexpected titana acylborane [Cp2Ti(L)(η2-OCB(C6F5)3)] (1, L = CO, “O-outside” configuration; 2, L = THF, “O-inside” configuration) with the tris(perfluorophenyl)borane, as a Lewis acid, attached to the carbonyl carbon atom. The acylborane picture is strengthened by a theoretical calculation (ELF).
创建时间：
2016-08-26
