Polyatomic Anion Assistance in the Assembly of [2]Pseudorotaxanes
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https://figshare.com/articles/dataset/Polyatomic_Anion_Assistance_in_the_Assembly_of_2_Pseudorotaxanes/2508280
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资源简介:
We describe the use of polyatomic anions for the quantitative
assembly
of ion-paired complexes displaying pseudorotaxane topology. Our approach
exploits the unique ion-pair recognition properties exhibited by noncovalent
neutral receptors assembled through hydrogen-bonding interactions
between a bis-calix[4]pyrrole macrocycle and linear bis-amidepyridyl-N-oxides. The complexation of bidentate polyatomic anions
that are complementary in size and shape to the receptor’s
cavity, in which six NH hydrogen-bond donors converge, induces the
exclusive formation of four particle-threaded assemblies.
创建时间:
2012-07-04



