Regio- and Diastereoselective Indium-Catalyzed Conia-Ene Reaction of ortho-Alkynyl Diketopiperazines to Access Fused Diketopiperazinoindolines
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https://figshare.com/articles/dataset/Regio-_and_Diastereoselective_Indium-Catalyzed_Conia-Ene_Reaction_of_i_ortho_i_-Alkynyl_Diketopiperazines_to_Access_Fused_Diketopiperazinoindolines/12554795
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资源简介：
An efficient synthesis of diketopiperazinoindolines through an indium-catalyzed intramolecular 5-exo-dig cyclization of ortho-alkynyl diketopiperazines has been reported. The formation of diketopiperazinoindolines proceeds via a regio- and diastereoselective Conia-ene reaction. This synthetic method opens a new door for easy access to functionalized fused diketopiperazinoindolines in high to excellent yields with exclusive Z diastereoselectivity.
创建时间：
2020-06-16
