A Zwitterionic Gold(I) Complex from an Ambiphilic Diphosphino−Alane Ligand
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https://figshare.com/articles/dataset/A_Zwitterionic_Gold_I_Complex_from_an_Ambiphilic_Diphosphino_Alane_Ligand/2942644
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资源简介：
The diphosphino−alane ligand ClAl[C6H4(o-P-i-Pr2)]2 (1) has been prepared and reacted with [AuCl(SMe2)]. X-ray analyses and DFT calculations substantiate the preference of the ensuing complex 2 for a zwitterionic structure, resulting from internal chloride abstraction by aluminum over a neutral form featuring an Au→Al interaction.
创建时间：
2016-02-27
