Bulky, Optically Active P-Stereogenic Phosphine–Boranes from Pure H-Menthylphosphinates
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https://figshare.com/articles/dataset/Bulky_Optically_Active_P_Stereogenic_Phosphine_Boranes_from_Pure_H_Menthylphosphinates/2629394
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The transformation of readily available pure-H-menthylphosphinates into chiral phosphinous acid-boranes permits the elaboration of bulky P-stereogenic secondary phosphine–boranes. Taking advantage of the synthetic potential of these compounds, a broad range of hindered P-chiral tertiary phosphine–boranes has been prepared with excellent enantiomeric excesses. The utility of bulky o-tolylphosphines was illustrated by the synthesis of a rare enantiopure phosphapalladacycle (SP,SP)-12.
创建时间：
2016-02-23
