Regio- and Enantioselective Allylic Alkylation of Terminal Alkynes by Synergistic Rh/Cu Catalysis
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下载链接：
https://figshare.com/articles/dataset/Regio-_and_Enantioselective_Allylic_Alkylation_of_Terminal_Alkynes_by_Synergistic_Rh_Cu_Catalysis/12866943
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资源简介：
A highly branch-
and enantioselective 1,4-enynes synthesis from
readily available terminal alkynes and racemic allylic carbonates
by Sonogashira type synergistic Rh and Cu catalysis under neutral
conditions has been developed. Aliphatic and aromatic terminal alkynes
with various functional groups could be used directly. An inner-sphere
reductive elimination C(sp)–C(sp3) bond formation
mechanism is supported by the stoichiometric reaction.
创建时间：
2020-08-20
