Total Synthesis of Enantiopure Chabrolonaphthoquinone B Via a Stereoselective Julia-Kocienski Olefination
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https://figshare.com/articles/dataset/Total_Synthesis_of_Enantiopure_Chabrolonaphthoquinone_B_Via_a_Stereoselective_Julia-Kocienski_Olefination/14956823
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资源简介：
The total synthesis of cytotoxic
meroditerpenoid naphthoquinone
derivative chabrolonaphthoquinone B (1) in an enantiospecific
manner is divulged using a chiral pool approach. The key step of our
synthetic route is a modified Julia olefination between a sulfone-bearing
aliphatic fragment and a Diels–Alder-derived aromatic aldehyde,
leading to the stereoselective construction of the E-trisubstituted double bond.
创建时间：
2021-07-12
