Access to [4,3,1]-Bridged Carbocycles via Rhodium(III)-Catalyzed C–H Activation of 2‑Arylindoles and Annulation with Quinone Monoacetals
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https://figshare.com/articles/dataset/Access_to_4_3_1_-Bridged_Carbocycles_via_Rhodium_III_-Catalyzed_C_H_Activation_of_2_Arylindoles_and_Annulation_with_Quinone_Monoacetals/11907729
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资源简介：
Reported
herein is the Rh(III)-catalyzed annulation of N-unprotected 2-arylindoles
with quinone monoacetals for the straightforward synthesis of [4,3,1]-bridged
carbocycles with exclusive C(3) selectivity. Mechanistic studies,
particularly deuterium-labeling experiments, suggest that the coupling
likely proceeds via two-fold C–H activation with two-fold migratory
insertion into the enone moieties.
创建时间：
2020-02-18
