Oxidative Access via Aqua Regia to an Electrophilic, Mesoionic Dicobaltoceniumyltriazolylidene Gold(III) Catalyst
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下载链接:
https://figshare.com/articles/dataset/Oxidative_Access_via_Aqua_Regia_to_an_Electrophilic_Mesoionic_Dicobaltoceniumyltriazolylidene_Gold_III_Catalyst/10286885
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资源简介:
A gold(III)
complex with the hitherto most electron poor mesoionic carbene ligand
is presented. Aqua regia was the oxidizing agent of choice for the
synthesis of this unusual organometallic compound. The AuIII complex is redox-rich and also acts as a catalyst for oxazole formation,
delivering selectively a completely different isomer in comparison
to its AuI congener.
创建时间:
2019-11-11



