A New Class of Constrained-Geometry Metallocenes: Synthesis and Crystal Structure of a Carboranyl−Thiol-Appended Half-Sandwich Titanocene and Its Conversion to Halotitanocene
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https://figshare.com/articles/dataset/A_New_Class_of_Constrained_Geometry_Metallocenes_Synthesis_and_Crystal_Structure_of_a_Carboranyl_Thiol_Appended_Half_Sandwich_Titanocene_and_Its_Conversion_to_Halotitanocene/3359125
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资源简介：
A novel carboranyl−thiol-appended cyclopentadiene ligand, 1-SH-2-[HCpCH(Ph)]-closo-1,2-C2B10H10 (2), was prepared and then reacted with
Ti(NMe2)4 to form the corresponding titanium complex
[1-(σ-S)-2-(η5-C5H4CH(Ph))-1,2-C2B10H10)]Ti(NMe2)2 (3),
which undergoes exclusively a monohalogenation reaction on the metal center, in the presence of Me3SiCl or
Me3NHCl, leading to the formation of [1-(σ-S)-2-(η5-C5H4CH(Ph))-1,2-C2B10H10)]TiCl(NMe2) (4) in 71% yield.
创建时间：
2016-05-07
