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Concise Asymmetric Total Synthesis of 9-epi-Sessilifoliamide J

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Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Concise_Asymmetric_Total_Synthesis_of_9_i_epi_i_Sessilifoliamide_J/2605882
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A 10-step asymmetric synthesis of 9-epi-sessilifoliamide J (20), together with sessilifoliamide J (6), has been accomplished from the key chiral building block 11 via a threo-selective vinylogous Mannich reaction and a Ley oxidation-SmI2-mediated coupling lactonization. The absolute configuration of the natural sessilifoliamide J was established.
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2016-02-22
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