Regioselective Synthesis of Functionalized Dihydropyrones via the Petasis Reaction
收藏Figshare2019-12-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Regioselective_Synthesis_of_Functionalized_Dihydropyrones_via_the_Petasis_Reaction/11461416
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资源简介：
A novel synthesis methodology for the construction of functionalized dihydropyrones has been developed with amines, glyoxylic acid, and 4-substituted-1,2-oxaborol-2(5H)-ols from the Petasis reaction. Mechanistic investigation indicated the intermolecular SN2 cyclization to provide 3,6-dihydro-2H-pyran-2-ones (3,6-DHP) and 5,6-dihydro-2H-pyran-2-ones (5,6-DHP) in one step with moderate to excellent yields.
创建时间：
2019-12-19
