Synthesis of Sexithiophene-Bridged Cage Compound: A New Class of Three-Dimensionally Expanded Oligothiophenes
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https://figshare.com/articles/dataset/Synthesis_of_Sexithiophene_Bridged_Cage_Compound_A_New_Class_of_Three_Dimensionally_Expanded_Oligothiophenes/2233072
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A bicyclo-type cage-shaped compound consisting of three sexithiophenes was successfully synthesized and characterized by NMR, HRMS, and X-ray crystallographic analysis. The strained cage architecture was reflected in the blue-shifted absorption spectrum relative to its linear analogue. Intramolecular interaction between three-dimensionally fixed sexithiophenes was suggested by electrochemical analysis.
创建时间：
2016-02-16
