Catalytic Asymmetric Oxidative α‑C–H N,O-Ketalization of Ketones by Chiral Primary Amine
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https://figshare.com/articles/dataset/Catalytic_Asymmetric_Oxidative_C_H_N_O_Ketalization_of_Ketones_by_Chiral_Primary_Amine/2200435
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资源简介：
A highly enantioselective primary
amine catalyzed α,α-bis-functionalization
of β-ketocarbonyls and cyclohexanones is described. This transformation
employs N-hydroxycarbamates as both nitrogen
and oxygen sources under aerobic oxidative conditions to furnish chiral
N,O-ketals with high yields and enantioselectivities.
创建时间：
2015-09-04
