Zn<sub>7</sub>O<sub>2</sub>(RCOO)<sub>10</sub> Clusters and Nitro Aromatic Linkers in a Porous Metal–Organic Framework
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A new metal–organic framework, CALF-22 comprising Zn7O2(COO)10 secondary building units and 2-nitro-1,4-benzenedicarboxylate, is reported. The porosity and gas adsorption of N2, H2, CO2, and CH4 are studied, and CALF-22 has a surface area in excess of 1000 m2/g. The stability of the larger zinc cluster and the effect of the nitro group on gas sorption are also studied.
创建时间：
2016-02-19
