Three-Coordinate β-Diketiminato Nickel Nitrosyl Complexes from Nickel(I)−Lutidine and Nickel(II)−Alkyl Precursors
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https://figshare.com/articles/dataset/Three_Coordinate_Diketiminato_Nickel_Nitrosyl_Complexes_from_Nickel_I_Lutidine_and_Nickel_II_Alkyl_Precursors/3361828
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资源简介：
The nickel(I) β-diketiminates [Me2NN]Ni(2,4-lutidine) and [2,4,6-Me3NN]Ni(2,4-lutidine) react with
NO to form diamagnetic, three-coordinate Ni−NO complexes, and [Me2NN]Ni(NO) undergoes insertion with a
nitrosobenzene to form the N-aryl-N-nitrosohydroxylaminato species [Me2NN]Ni(η2-O2N2Ar). Addition of 2
equiv of NO to the Ni(II)−monoalkyl species [Me2NN]Ni(Et)(2,4-lutidine) at room temperature provides an
alternate route to [Me2NN]Ni(NO), while NO addition
at −78 °C favors the formation of [Me2NN]Ni(η2-O2N2Et).
创建时间：
2016-05-07
