Benzo-21-crown-7-Based [1]Rotaxanes: Syntheses, X‑ray Crystal Structures, and Dynamic Characteristics
收藏Figshare2016-02-18 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Benzo_21_crown_7_Based_1_Rotaxanes_Syntheses_X_ray_Crystal_Structures_and_Dynamic_Characteristics/2365402
下载链接
链接失效反馈官方服务：
资源简介：
Two B21C7-based [1]rotaxanes were synthesized in high yields by means of copper(II)-mediated Eglinton coupling and a subsequent Pd/C-catalyzed reduction under H2. X-ray single-crystal analysis shows that [1]rotaxane takes on a self-entangled conformation, wherein the macrocycle is threaded by its own tail. Moreover, it was found that [1]rotaxane with a flexible skeleton had more rotational motions than that of one with a rigid skeleton.
创建时间：
2016-02-18
