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Metal-Complex-Decorated Homochiral Heterobimetallic Telluride Single-Stranded Helix

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https://figshare.com/articles/dataset/Metal_Complex_Decorated_Homochiral_Heterobimetallic_Telluride_Single_Stranded_Helix/2988073
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Solvothermal reaction of a mixture of Sn, Mn, and Te at 200 °C using teta as the solvent yields a novel inorganic−organic hybrid solid [Mn(teta)(en)]·[Mn(teta)][Mn(SnTe4)2·Mn(teta)] (teta = triethylenetetramine and en = ethylenediamine; 1), which has a homochiral single-stranded helical structure. The material is a semiconductor with a band gap of 0.88 eV and shows paramagnetic behavior between 2 and 300 K.
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2016-06-03
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