Capturing C84 Isomers as Chlorides and Pentafluoroethyl Derivatives: C84Cl22 and C84(C2F5)12
收藏Figshare2016-02-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Capturing_C_sub_84_sub_Isomers_as_Chlorides_and_Pentafluoroethyl_Derivatives_C_sub_84_sub_Cl_sub_22_sub_and_C_sub_84_sub_C_sub_2_sub_F_sub_5_sub_sub_12_sub_/2544346
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资源简介：
A mixture of higher fullerenes C76–C96 was pentafluoroethylated with C2F5I at 250 °C affording a mixture of C2F5 derivatives. After separation with high-performance liquid chromatography, the second C2F5 derivative of C84(16), C84(C2F5)12, was investigated by X-ray crystallography and compared with the known isomer in terms of addition patterns and formation energies. Chlorination of a C84 isomeric mixture with VCl4 at 350–400 °C resulted in the formation of C84Cl22. X-ray diffraction study revealed the superposition of several C84Cl22 molecules with different isomeric C84 cages but the same chlorination pattern.
创建时间：
2016-02-22
