A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene
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https://figshare.com/articles/dataset/A_Facile_Route_to_Functionalized_N_Heterocyclic_Carbenes_NHCs_with_NHC_Base_Stabilized_Dichlorosilylene/2748454
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资源简介：
Reaction of IPr·SiCl2 (1) [IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene] with 1-azidoadamantane leads to functionalized N-heterocyclic carbene (NHC) 2. Silyl-substituted NHC 2 reacts easily with 1-azidoadamantane to form triazene 3, in which the exocyclic CN bond is slightly shorter than those of regular NHC-derived triazines. 2 could serve as a promising ligand for transition metals.
创建时间：
2010-07-28
