Strained and Unstrained Macrocycles Composed of Carbazole and Butadiyne Units: Electronic State and Optical Properties
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https://figshare.com/articles/dataset/Strained_and_Unstrained_Macrocycles_Composed_of_Carbazole_and_Butadiyne_Units_Electronic_State_and_Optical_Properties/2521438
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资源简介：
Cu(OAc)2 catalyzes dehydrogenative condensation
of 3,6-bis(2-ethynylphenyl)carbazole
in the presence of O2 to afford the cyclization product 1 and cyclodimer 2. Compound 1 contains
bent carbazole and butadiyne groups, while 2 has a less
strained structure with Z shape around the two parallel butadiyne
groups. Optical properties of the compounds are discussed based on
the electronic states estimated from electrochemical measurement and
density functional theory calculation.
创建时间：
2016-02-20
