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Highly Stereoselective Olefin Cyclopropanation of Diazooxindoles Catalyzed by a C2‑Symmetric Spiroketal Bisphosphine/Au(I) Complex

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Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Highly_Stereoselective_Olefin_Cyclopropanation_of_Diazooxindoles_Catalyzed_by_a_i_C_i_sub_2_sub_Symmetric_Spiroketal_Bisphosphine_Au_I_Complex/2409820
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A spiroketal bisphosphine (SKP) derived chiral digold complex is identified as a powerful catalyst for the highly diastereo- and enantioselective synthesis of spirocyclopropyloxindoles from diazooxindoles and a broad range of alkenes, including both cis and trans 1,2-disubstituted alkenes.
创建时间:
2016-02-19
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