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The First Palladium(0) Complex of a Linear 1,6,11-Triyne. A Reactive Intermediate in the Catalytic Cyclotrimerization of a Triyne

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/The_First_Palladium_0_Complex_of_a_Linear_1_6_11-Triyne_A_Reactive_Intermediate_in_the_Catalytic_Cyclotrimerization_of_a_Triyne/3762702
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The reaction of Pd2(dba)3·CHCl3 with dimethyl 4,9-dioxatrideca-2,7,12-triyne-1,13-dioate gave the first palladium(0) triyne complex in good yield. The triyne complex was confirmed to be an efficient catalyst precursor for the cyclization of the triyne ligand.
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2016-08-26
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