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Incommensurate Nature of the Multilayered Molecular Ferromagnetic Metals Based on Bis(ethylenedithio)tetrathiafulvalene and Bimetallic Oxalate Complexes

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https://figshare.com/articles/dataset/Incommensurate_Nature_of_the_Multilayered_Molecular_Ferromagnetic_Metals_Based_on_Bis_ethylenedithio_tetrathiafulvalene_and_Bimetallic_Oxalate_Complexes/3329377
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The salt [ET]x[MnRh(ox)3]·CH2Cl2 (x = 2.526(1)) has been obtained and characterized. This paramagnetic metal is essentially isostructural to the ferromagnetic metal [ET]y[MnCr(ox)3]·CH2Cl2 (y ≈ 3) and provides a definite answer on the origin of the structural disorder present on such systems. As in the ferromagnetic analogue, this material shows high electrical conductivity at room temperature (13 S·cm-1) and metallic behavior.
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2016-05-06
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