Ligand- and Base-Free Pd(II)-Catalyzed Controlled Switching between Oxidative Heck and Conjugate Addition Reactions
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Ligand_and_Base_Free_Pd_II_Catalyzed_Controlled_Switching_between_Oxidative_Heck_and_Conjugate_Addition_Reactions/2422693
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资源简介：
A simple change of solvent allows controlled and efficient switching between oxidative Heck and conjugate addition reactions on cyclic Michael acceptor substrates, catalyzed by a cationic Pd(II) catalyst system. Both reactions are ligand- and base-free and tolerant of air and moisture, and the controlled switching sheds light on some of the factors which favor one reaction over the other.
创建时间：
2016-02-19
