Infinite Three-Dimensional Polymeric Metalloporphyrin Network via Six-Coordinate Zn(II) and Two Axial Oxygen Donors
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https://figshare.com/articles/dataset/Infinite_Three_Dimensional_Polymeric_Metalloporphyrin_Network_via_Six_Coordinate_Zn_II_and_Two_Axial_Oxygen_Donors/3360904
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资源简介：
An X-ray crystallographic study of zinc(II) 5,15-di-(2-methoxymethylphenyl)-porphyrin indicates that it forms a coordination polymer through
ligation of the ether oxygen atoms on the porphyrin peripheries to the metal centers of two identical adjacent porphyrins. This gives a novel
extensively linked, three-dimensional polymeric structure in which the zinc(II) metal forms a six-coordination center. The uniquely structured
network has cavities between 4.81 and 9.27 Å, which makes it resemble molecular sieve materials.
创建时间：
2016-05-07
