Lithiation of Diamine Ligands to Chiral Building Blocks: Syntheses, Selectivities, and Lithiated Intermediates
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/Lithiation_of_Diamine_Ligands_to_Chiral_Building_Blocks_Syntheses_Selectivities_and_Lithiated_Intermediates/2777953
下载链接
链接失效反馈官方服务：
资源简介：
The direct deprotonation of the chiral nitrogen ligands (R,R)-TECDA (2) and (R,R)-TEMCDA (6) with tert-butyllithium to highly reactive building blocks is reported. The regioselectivity of the lithiation reactions can be explained by the isolated precoordinated intermediates such as tBuLi·(R,R)-TECDA in combination with computational studies.
创建时间：
2010-04-12
