Fully amorphous atactic and isotactic block copolymers and their self-assembly into nano- and microscopic vesicles
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Data underlying the figures in the publication “Fully amorphous atactic and isotactic block copolymers and their self-assembly into nano- and microscopic vesicles”, published in <em>Polym. Chem., </em><em><strong>2021</strong></em><em>, 12, 5377-5389</em>. https://pubs.rsc.org/en/content/articlelanding/2021/PY/D1PY00952D Table of contents: <strong>1. Figure 1</strong>: Zip archive containing the experimental data (NMR spectra) for the kinetics of the PBO syntheses (<em>Figure 1c</em>) and the PBO-b-PEEGE syntheses (<em>Figure 1d</em>). <strong>2. Figure 2</strong>: Zip archive containing the experimental data for <em>Figure 2</em>. Structural characterisation of the (S)-BCP (S)-PBO<sub>27</sub>-b-(S)-PG<sub>14</sub> by <sup>1</sup>H-NMR spectroscopy in methanol-d<sub>4</sub>. <strong>3. Figure 3</strong>: Zip archive containing the experimental data for <em>Figure 3</em>. Chiral characterisation of the atactic and isotactic BCPs. <strong>4. Figure 4</strong>: Zip archive containing the experimental data for <em>Figure 4</em>. TEM and Cryo-TEM characterisation of the SUVs formed by <em>(a)</em> (R/S)-PBO<sub>26</sub>-b-(R/S)-PG<sub>14</sub>, <em>(b)</em> (R)-PBO<sub>26</sub>-b-(R)-PG<sub>14</sub> and <em>(c)</em> (S)-PBO<sub>27</sub>-b-(S)-PG<sub>14</sub>. <strong>5. Figure 5</strong>: Zip archive containing the CLSM images for <em>Figure 5</em>. <strong>6. Figure 6</strong>: Zip archive containing the images for <em>Figure 6</em>. Snapshots of the enzyme reaction within the cavity of (R/S)-BCP GUVs <em>(b)</em> with and <em>(c)</em> without reconstituted membrane protein OmpF, recorded by CLSM at different time points <strong>7. Figure 7</strong>: Excel file containing the experimental data for <em>Figure 7</em>. Fluorescence intensity development of <em>(a)</em> (R/S)-BCP and <em>(b)</em> PDMS<sub>25</sub>-b-PMOXA<sub>10</sub> GUVs resulting from the reaction of resorufin β-D-galactopyranoside (RGP) with β-galactosidase (β-Gal) to yield fluorescent resorufin. <strong>8. Table 1</strong>: Zip archive containing the experimental data for <em>Table 1</em>. <strong>9. Table 2</strong>: Zip archive containing the experimental data for <em>Table 2</em>.
