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“Electronic Lock” in Chromiumtricarbonyl Complex of Cycloheptatrienyltin

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https://figshare.com/articles/dataset/_Electronic_Lock_in_Chromiumtricarbonyl_Complex_of_Cycloheptatrienyltin/3357736
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资源简介:
The fast sigmatropic [1,5]-Sn migration in cycloheptatrienyl(triphenyl)tin is effectively locked in the chromiumtricarbonyl complex. A much slower [1,3]-Sn + [1,2]-Cr diatropic rearrangement was detected by spin saturation transfer NMR.
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2016-05-07
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