“Electronic Lock” in Chromiumtricarbonyl Complex of Cycloheptatrienyltin
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The fast sigmatropic [1,5]-Sn migration in cycloheptatrienyl(triphenyl)tin is effectively locked in the chromiumtricarbonyl complex. A much slower [1,3]-Sn + [1,2]-Cr diatropic rearrangement was detected by spin saturation transfer NMR.
创建时间：
2016-05-07
