New Preparation of 1,2,4,5,7,8-Hexaoxonanes
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https://figshare.com/articles/dataset/New_Preparation_of_1_2_4_5_7_8_Hexaoxonanes/2985790
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资源简介:
A new versatile procedure was developed for the synthesis of 1,2,4,5,7,8-hexaoxonanes based on the
Lewis acid catalyzed reaction of acetals with 1,1‘-dihydroperoxydicycloalkyl peroxides. The procedure
substantially extends the structural diversity of these compounds and, in most cases, allows the synthesis
of these compounds in higher yields (to 96%) and with higher selectivity. Complexation of hexaoxonane
with chloroform was documented for the first time. The structures of several triperoxides were established
by X-ray diffraction.
创建时间:
2016-06-03



