Octacyclo[10.6.1.01,10.03,7.04,9.08,19.011,16.013,17]nonadeca-5,8,14-triene (27), a hindered pyramidalized alkene, has been generated from a diiodide precursor. Contrary to the usual behavior of kno
The synthesis and the characterization of a series of phosphine adducts of (imido)vanadium(IV) dichloride complexes of the type V(NR)Cl2(PMe2Ph)2 [R = 2,6-Cl2-Ph (1), 2,6-iPr2-Ph (2), and tBu (3)
Metal-free dioxygenation of alkenes with tert-butyl nitrite and N-hydroxylamines (N-hydroxyphthalimide, N-hydroxybenzotriazole, and N-hydroxysuccinimide) is described to produce β-aminoxy nitrate este
Reaction of Mo(NAr)(CHCMe2Ph)(OTf)2(DME) (Ar = 2,6-i-Pr2C6H3) with the lithium salt of various β-diketonates and β-diketiminates leads to complexes of the type Mo(NAr)(CHCMe2Ph)(L)(OTf) (L = β-diketon
[Fe(Me2EBC)(OTf)2], the iron(II) complex of the tetraazamacrocyclic Me2EBC ligand (Me2EBC = 4,11-dimethyl-1,4,8,11-tetraazabicyclo [6.6.2]hexadecane), has been investigated as a catalyst for olefin ox