Highly Ordered Phenanthroline-Fused Azaacene
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https://figshare.com/articles/dataset/Highly_Ordered_Phenanthroline_Fused_Azaacene/2113540
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资源简介：
A new synthetic route to prepare
a centrosymmetric phenanthroline-fused
azaacene derivative, TIPS-BisPhNPQ, is described. Another
axialsymmetric analogue, TIPS-PhNTQ, is also synthesized
for comparison. Cyclic voltammetry measurements indicate high electron
affinity values of −4.03 and −4.01 eV for TIPS-PhNTQ and TIPS-BisPhNPQ, respectively. Single-crystal X-ray
diffraction reveals that TIPS-PhNTQ forms dimers by intermolecular
S–N and N–N interaction, while TIPS-BisPhNPQ shows a highly ordered arrangement via two-dimensional brickwork
packing and intermolecular hydrogen bonding. The synthetic protocol
established in this paper should be highly applicable to the preparation
of more azaacene derivatives with extended π-conjugations.
创建时间：
2016-02-12
