Crystal Engineering with Modified 2‑Aminopurine and Group 12 Metal Ions
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https://figshare.com/articles/dataset/Crystal_Engineering_with_Modified_2_Aminopurine_and_Group_12_Metal_Ions/2399479
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资源简介：
This communication describes the
synthesis and structure of zinc,
cadmium, and mercury complexes of modified N9-substituted 2-aminopurine
(2AP) analogues. 2AP is an inherently fluorescent heterocyclic nucleobase
with wide applications in biochemical reactions. Herein, we report
a one-dimensional (1D) polymeric helical chain and discrete arrangements
for zinc complexes [C8H11N5Cl2Zn] (1) and [C12H15N5O5Zn] (2), a 1D polymeric helical
chain for a Cd complex [C8H11CdI2N5] (3), and a unique example of supported
2AP-Hg(II) two-dimensional clusters [C16H21Cl6Hg3N10] (4). The photoluminescence
properties of free ligand L and complexes 1–4 are also presented.
创建时间：
2013-07-03
