<i>s</i>-<i>trans</i>-Diene Complexes of a First-Row Transition Metal. Half-Sandwich <i>s</i>-<i>trans</i>-η<sup>4</sup>-1,3-Diene Nitrosyl Complexes of Chromium
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The first s-trans-1,3-diene complexes of a first-row transition metal have been prepared and characterized both in solution and in the solid state. The unexpected s-trans configuration was obtained from photolytic decarbonylation of Cp‘Cr(NO)(CO)2 (Cp‘ = η5-C5H5 and η5-C5Me5) in the presence of conjugated dienes. Related η2-olefin and η2-2-alkyne complexes have also been prepared.
创建时间：
2016-05-12
