Reactions of (η5-C5Me5)Ir(PMe3)(SH)2 and (η5-C5Me5)Ir(PMe3)(SH)(H) with Thionylaniline (PhNSO) to Give Novel Iridium S3O and S2O Complexes
收藏Figshare2007-08-13 更新2026-04-28 收录
下载链接：
https://figshare.com/articles/dataset/Reactions_of_sup_5_sup_-C_sub_5_sub_Me_sub_5_sub_Ir_PMe_sub_3_sub_SH_sub_2_sub_and_sup_5_sup_-C_sub_5_sub_Me_sub_5_sub_Ir_PMe_sub_3_sub_SH_H_with_Thionylaniline_PhNSO_to_Give_Novel_Iridium_S_sub_3_sub_O_and_S_sub_2_sub_O_Complexes/12064944
下载链接
链接失效反馈官方服务：
资源简介：
Treatment of Cp*Ir(PMe3)(SH)2 (1), where Cp* = η5-C5Me5, with thionylaniline (PhNSO), CS2, and p-tolylisothiocyanate (p-tolNCS) gave Cp*Ir(PMe3)(S3O) (3), Cp*Ir(PMe3)(S2CS) (4), and Cp*Ir(PMe3)(SH)(SC(S)HN-p-tol) (5), respectively. Treatment of Cp*Ir(PMe2R)(H)(SH) (2a,b), where R = Me (2a), Ph (2b), with PhNSO gave Cp*Ir(PMe2R)(S2O) (6a,b) as mixtures of interconvertible conformational isomers. Treatment of 2a with p-tolNCS gave Cp*Ir(PMe3)(H)(SC(S)NH-p-tol) (7). The crystal structures of 3−5, 6b, and 7 are reported.
创建时间：
2007-08-13
