Synthesis and Structure of Asymmetric Zirconium-Substituted Silicotungstates, [Zr<sub>6</sub>O<sub>2</sub>(OH)<sub>4</sub>(H<sub>2</sub>O)<sub>3</sub>(β-SiW<sub>10</sub>O<sub>37</sub>)<sub>3</sub>]<sup>14-</sup> and [Zr<sub>4</sub>O<sub>2</sub>(OH)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>(β-SiW<sub>
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数据链接：
https://figshare.com/articles/dataset/Synthesis_and_Structure_of_Asymmetric_Zirconium_Substituted_Silicotungstates_Zr_sub_6_sub_O_sub_2_sub_OH_sub_4_sub_H_sub_2_sub_O_sub_3_sub_SiW_sub_10_sub_O_sub_37_sub_sub_3_sub_sup_14_sup_and_Zr_sub_4_sub_O_sub_2_sub_OH_sub_2_sub_H_sub_2_sub_O_sub_4_sub_S/3232465数据链接链接失效反馈
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资源简介：
The reaction of ZrCl4 with [γ-SiW10O36]8- in a potassium acetate buffer results in two different products depending on the reactant ratios. The trimeric species [Zr6O2(OH)4(H2O)3(β-SiW10O37)3]14- (1) consists of three β23-SiW10O37 units linked by an unprecedented Zr6O2(OH)4(H2O)3 cluster with C1 point group symmetry. The dimeric species [Zr4O2(OH)2(H2O)4(β-SiW10O37)2]10- (2) consists of β22- and β12-SiW10O37 units sandwiching a Zr4O2(OH)2(H2O)4 cluster, which also has C1 symmetry. Polyanion 1 contains more zirconium centers than any other polyoxometalate known to date.
创建时间：
2006-03-20
