A New Supporting Ligand in Actinide Chemistry Leads to Reactive Bis(NHC)borate-Supported Thorium Complexes
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https://figshare.com/articles/dataset/A_New_Supporting_Ligand_in_Actinide_Chemistry_Leads_to_Reactive_Bis_NHC_borate-Supported_Thorium_Complexes/3749796
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资源简介：
A versatile,
monoanionic, chelating (bis)carbene ligand (2) was used
to prepare a thorium dihalide complex (3) and a direduced-bpy
derivative (4). CASSCF calculations
suggest the involvement of a multiconfigurational open-shell singlet,
with the main configuration corresponding to a Th(III)-bpy(−1)
(f1π*1) electronic structure. The reactivity
of 4 was explored in various transformations, including
reactions with carbonyls and organic azides; the latter gave rise
to an unusual terminal Th-imido bpy complex (6).
创建时间：
2016-09-21
