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Asymmetric α‑Sulfonyl- and α‑Phosphoryl-Oxylation of Ketones by a Chiral Hypervalent Iodine(III)

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NIAID Data Ecosystem2026-03-10 收录
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https://figshare.com/articles/dataset/Asymmetric_Sulfonyl-_and_Phosphoryl-Oxylation_of_Ketones_by_a_Chiral_Hypervalent_Iodine_III_/5261605
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资源简介:
An enantioselective direct oxygenation of propiophenone derivatives mediated by a catalytic or stoichiometric amount of new chiral non-C2-symmetric iodoarenes­(III) is reported. The reaction gives an easy entry to optically active α-sulfonyl- and α-phosphoryl oxyketones in respectable yields and enantioselectivities.
创建时间:
2017-07-31
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