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A Ferromagnetic Salicylaldoximate/Azide Mn<sup>II</sup><sub>2</sub>Mn<sup>III</sup><sub>6</sub> Cluster with an <i>S</i> = 17 Ground State and a Single-Molecule-Magnet Response

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One new MnII2MnIII6 cluster exhibiting an S = 17 spin ground state and single-molecule-magnet properties has been designed linking MnIII3-salicylaldoximate triangles and tetracoordinated MnII cations by means of end-on azido bridges. The ferromagnetic coupling has been rationalized as a function of their structural parameters.

创建时间:
2016-06-14
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