Individual assembly of two-species Rydberg molecules using optical tweezers [dataset]

We present a new approach to investigating Rydberg molecules by demonstrating the formation and characterization of individual Rb*Cs Rydberg molecules using optical tweezers. By employ- ing single-atom detection of Rb and Cs, we observe molecule formation via correlated loss of both species and study the formation dynamics with single-particle resolution. We control the interatomic distances by manipulating the relative wavefunction of atom pairs using the tweezer intensity, op- timizing the coupling to molecular states and exploring the effect of the tweezer on these states. Additionally, we demonstrate molecule association with atoms trapped in separate tweezers, paving the way for state-selective assembly of polyatomic molecules. The observed binding energies, molec- ular alignment, and bond lengths are in good agreement with theory. Our approach is broadly applicable to Rydberg tweezer platforms, expanding the range of available molecular systems and enabling the integration of Rydberg molecules into existing quantum science platforms.