Stereoselective Synthesis of 1,3-Amino Alcohols by the Pd-Catalyzed Cyclization of Trichloroacetimidates
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https://figshare.com/articles/dataset/Stereoselective_Synthesis_of_1_3_Amino_Alcohols_by_the_Pd_Catalyzed_Cyclization_of_Trichloroacetimidates/2325043
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资源简介：
The
synthesis of 4-vinyl-5,6-dihydro-1,3-oxazines, precursors of
1,3-amino alcohols, using the palladium-catalyzed cyclization of trichloroacetimidates
is reported. The reaction favors the formation of the
4,6-cis-isomers with up to >20:1 diastereoselectivity.
Chemoselective hydrolysis of the resulting 5,6-dihydro-1,3-oxazines
was also investigated.
创建时间：
2016-02-18
