Intramolecular Dearomatizing [3 + 2] Annulation of α‑Imino Carbenoids with Aryl Rings Furnishing 3,4-Fused Indole Skeletons
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The rhodium-catalyzed dearomatizing [3 + 2] annulation reaction of 4-(3-arylpropyl)-1,2,3-triazoles is described. It provides a straightforward synthetic pathway from simple 5-aryl-1-alkynes leading to tricyclic 3,4-fused dihydroindoles via the corresponding 1,2,3-triazoles.
创建时间：
2016-02-18
