Synthesis of the C<sub>59</sub>N<sup>+</sup> Carbocation. A Monomeric Azafullerene Isoelectronic to C<sub>60</sub>
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A heterofullerene isoelectronic to C60 is reported. The azafullerenium cation C59N+ can be isolated in good yield as a carborane salt via the two-electron oxidation of the C−C bond of (C59N)2 dimer. [C59N][Ag(CB11H6Cl6)2] has been characterized by electronic, IR, Raman, and 13C NMR spectroscopies, MALDI spectrometry, DFT calculations, and X-ray crystallography.
创建时间：
2016-08-18
